Patents

  • Publication number: 20170150725
    Abstract: The present invention relates to the use of heteropolyoxometalates for disinfecting purposes and in antimicrobial surfaces, paints or coatings and intermediates for their preparation.
    Type: Application
    Filed: February 6, 2014
    Publication date: June 1, 2017
    Applicant: POM Patentverwaltungs GbR
    Inventors: Klaus Schepers, Horst Mischo, Pierre-Alain Weiss, Ulrich Kortz, Bassem S. Bassil, Maria Barsukova-Stuckart, Rami Al-Oweini, Andreas Suchopar, Ali Haider, Alexander Birkel, Balamurugan Kandasamy
  • Publication number: 20150373987
    Abstract: The present invention relates to the use of heteropolyoxometalates for disinfecting purposes and in antimicrobial surfaces, paints or coatings and intermediates for their preparation.
    Type: Application
    Filed: February 6, 2014
    Publication date: December 31, 2015
    Applicant: POM Patentverwaltungs GbR
    Inventors: Klaus Schepers, Horst Mischo, Pierre-Alain Weiss, Ulrich Kortz, Bassem S. Bassil, Maria Barsukova-Stuckart, Rami Al-Oweini, Andreas Suchopar, Ali Haider, Alexander Birkel, Balamurugan Kandasamy
  • Patent number: 8080493
    Abstract: The invention relates to polyoxometalates represented by the formula (An)m+ [M13X8RqOy]m? or solvates thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyanion, M represents a transition metal selected from Pd, Pt, Au, Rh, Ir and mixtures thereof, X represents a heteroatom selected from As, Sb, Bi, P, Si, Ge, B, Al, Ga, S, Se, Te and mixtures thereof, and y is the number of oxygen atoms ranging from 32 to 40, a process for their preparation and their use for the catalytic oxidation of organic molecules.
    Type: Grant
    Filed: February 26, 2008
    Date of Patent: December 20, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Elena Vladimirovna Chubarova, Ulrich Kortz
  • Patent number: 7906686
    Abstract: In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of a catalyst comprising a polyoxometalate to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I) and wherein the polyoxometalate comprises a polyoxotungstate substituted with at least one further transition metal.
    Type: Grant
    Filed: April 7, 2008
    Date of Patent: March 15, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Helge Jaensch, Jihad M. Dakka, Francisco M. Benitez, Ulrich Kortz, Ryan Matthew Richards
  • Patent number: 7858814
    Abstract: The invention relates to polyoxometalates represented by the formula (An)m+ [Ru2L2(XW11O39)2WO2]m? or solvates thereof, wherein A is a cation, n is the number of the cations, m is the charge of the polyanion, L is a ligand bound to ruthenium and is independently selected from group consisting of water, unsubstituted or substituted arenes, unsubstituted or substituted heteroarenes, unsaturated hydrocarbons, ethers, unsubstituted or substituted allyl, unsubstituted or substituted alkanes, nitriles, carboxylates, peroxides, peracids, phosphines, phosphanes, CO, OH?, peroxo, carbonate, NO3?, NO2?, NO?, NH3, amines, F?, Cl?, Br?, I?, SCN?, NCS?, NCO? and mixtures thereof and X is a heteroatom selected from Si, Ge, B and mixtures thereof, a process for their preparation and their use for the catalytic oxidation of organic molecules.
    Type: Grant
    Filed: June 20, 2008
    Date of Patent: December 28, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Ulrich Kortz, Elena Vladimirovna Chubarova, Nadeen Hassan Nsouli
  • Patent number: 7820868
    Abstract: This invention relates to polyoxometalates represented by the formula (An)m+[My(H2O)pXzZ2W18O66]m?1 or solvates thereof, wherein A represents a cation acting as counterion of the polyanion, n is the number of the cations A, m is the charge of the polyoxoanion, M represents a transition metal selected from Cu, Zn, Pd, Pt and mixtures thereof, y is the number of transition metals M and is a number from greater than 4 to less than 6, p is a number of water molecules and is a number from 0 to 10, X is a halide selected from F, Cl, Br, I and mixtures thereof, z is a number of halides and is a number from 0 to 6 and Z represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV.
    Type: Grant
    Filed: January 19, 2007
    Date of Patent: October 26, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Ulrich Kortz, Sib Sankar Mal
  • Publication number: 20100185016
    Abstract: In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of a catalyst comprising a polyoxometalate to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I) and wherein the polyoxometalate comprises a polyoxotungstate substituted with at least one further transition metal.
    Type: Application
    Filed: April 7, 2008
    Publication date: July 22, 2010
    Inventors: Helge Jaensch, Jihad M. Dakka, Francisco M. Benitez, Ulrich Kortz, Ryan Matthew Richards
  • Patent number: 7645907
    Abstract: This invention relates to a Polyoxometalate (POM) represented by the formula: (An)m+[HqM16X8W48O184(OH)32]m? or solvates thereof, wherein: A represents a cation, n is the number of the cations A, m is the charge of the polyoxoanion, q is the number of protons and varies from 0 to 12, M represents a transition metal, and X represents a heteroatom selected from P, As and mixtures thereof. This invention also relates to a process to produce such POMs and to a process for the homogeneous or heterogeneous oxidation of organic substrates comprising contacting the organic substrate with such POMs.
    Type: Grant
    Filed: March 23, 2007
    Date of Patent: January 12, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Ulrich Kortz, Sib Sankar Mal
  • Publication number: 20090318723
    Abstract: The invention relates to polyoxometalates represented by the formula (An)m+ [Ru2L2(XW11O39)2WO2]m? or solvates thereof, wherein A is a cation, n is the number of the cations, m is the charge of the polyanion, L is a ligand bound to ruthenium and is independently selected from group consisting of water, unsubstituted or substituted arenes, unsubstituted or substituted heteroarenes, unsaturated hydrocarbons, ethers, unsubstituted or substituted allyl, unsubstituted or substituted alkanes, nitriles, carboxylates, peroxides, peracids, phosphines, phosphanes, CO, OH?, peroxo, carbonate, NO3?, NO2?, NO?, NH3, amines, F?, Cl?, Br?, I?, SCN?, NCS?, NCO? and mixtures thereof and X is a heteroatom selected from Si, Ge, B and mixtures thereof, a process for their preparation and their use for the catalytic oxidation of organic molecules.
    Type: Application
    Filed: June 20, 2008
    Publication date: December 24, 2009
    Inventors: Ulrich Kortz, Elena Vladimirovna Chubarova, Nadeen Hassan Nsouli
  • Publication number: 20090216052
    Abstract: The invention relates to polyoxometalates represented by the formula (An)m+ [M13X8RqOy]m? or solvates thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyanion, M represents a transition metal selected from Pd, Pt, Au, Rh, Ir and mixtures thereof, X represents a heteroatom selected from As, Sb, Bi, P, Si, Ge, B, Al, Ga, S, Se, Te and mixtures thereof, and y is the number of oxygen atoms ranging from 32 to 40, a process for their preparation and their use for the catalytic oxidation of organic molecules.
    Type: Application
    Filed: February 26, 2008
    Publication date: August 27, 2009
    Inventors: Elena Vladimirovna Chubarova, Ulrich Kortz
  • Patent number: 7514577
    Abstract: The invention relates to polyoxometalates represented by the formula (An)m+ [My(H2O)(p.y)X2W22O74(OH)2]m? or solvates or mixtures thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyoxoanion, M represents a transition metal selected from Pd, Pt and mixtures thereof, y is 1, 2, 3 or 4, p is the number of water molecules bound to one M and varies from 3 to 5, and X represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV, a process for their preparation and their use for the catalytic oxidation of organic molecules.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: April 7, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Ulrich Kortz, Lihua Bi
  • Publication number: 20080233033
    Abstract: This invention relates to a Polyoxometalate (POM) represented by the formula: (An)m+[HqM16X8W48O184(OH)32]m? or solvates thereof, wherein: A represents a cation, n is the number of the cations A, m is the charge of the polyoxoanion, q is the number of protons and varies from 0 to 12, M represents a transition metal, and X represents a heteroatom selected from P, As and mixtures thereof. This invention also relates to a process to produce such POMs and to a process for the homogeneous or heterogeneous oxidation of organic substrates comprising contacting the organic substrate with such POMs.
    Type: Application
    Filed: March 23, 2007
    Publication date: September 25, 2008
    Inventors: Ulrich Kortz, Sib Sankar Mal
  • Patent number: 7417008
    Abstract: The invention relates to supported polyoxometalates represented by the formula (An)m+ [M4(H2O)10(XW9O33)2]m? or solvates thereof, wherein A represents a cation, n is the number of cations, m is the charge of the polyoxoanion, M is a transition metal, and X is an element selected from the group consisting of As, Sb, Bi, Se and Te, characterized in that the polyoxometalate is supported on a solid support selected from the group consisting of Al2O3, MgO, TiO2, ZrO2, SiO2, mesoporous silica, active carbon, diatomite, clays, zeolites, polyoxometalate salts and mixtures thereof, with the proviso that the polyoxometalate salt supports are different from the supported polyoxometalates defined by the above formula, a process for their preparation and their use for the catalytic oxidation of organic molecules.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: August 26, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Ryan M. Richards, Ulrich Kortz, Lihua Bi, Kake Zhu
  • Publication number: 20080177118
    Abstract: This invention relates to polyoxometalates represented by the formula (An)m+[My(H2O)pXzZ2W18O66]m? or solvates thereof, wherein A represents a cation acting as counterion of the polyanion, n is the number of the cations A, m is the charge of the polyoxoanion, M represents a transition metal selected from Cu, Zn, Pd, Pt and mixtures thereof, y is the number of transition metals M and is a number from greater than 4 to less than 6, p is a number of water molecules and is a number from 0 to 10, X is a halide selected from F, Cl, Br, I and mixtures thereof, z is a number of halides and is a number from 0 to 6 and Z represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV. This invention also relates to a method to make polyoxometalates represented by the formula (II): (An)m+[My(H2O)pXzZ2W18O66]m? or solvates thereof, where y is the number of transition metals M and is a number from greater than 4 to less than or equal to 6, and A, n, m, M p, X, z, Z, are as defined for formula (I).
    Type: Application
    Filed: January 19, 2007
    Publication date: July 24, 2008
    Inventors: Ulrich Kortz, Sib Sankar Mal
  • Patent number: 7358380
    Abstract: The invention relates to polyoxometalates represented by the formula (An)m+[R2(H2O)6X2W20O70]m? or solvates thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyoxoanion, and X represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV, a process for their preparation and their use for the catalytic oxidation of organic molecules.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: April 15, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Ulrich Kortz, Lihua Bi
  • Publication number: 20070282140
    Abstract: The invention relates to polyoxometalates represented by the formula (An)m+[R2(H2O)6X2W20O70]m? or solvates thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyoxoanion, and X represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV, a process for their preparation and their use for the catalytic oxidation of organic molecules.
    Type: Application
    Filed: May 31, 2006
    Publication date: December 6, 2007
    Inventors: Ulrich Kortz, Lihua Bi
  • Publication number: 20070282138
    Abstract: The invention relates to supported polyoxometalates represented by the formula (An)m+ [M4(H2O)10(XW9O33)2]m? or solvates thereof, wherein A represents a cation, n is the number of cations, m is the charge of the polyoxoanion, M is a transition metal, and X is an element selected from the group consisting of As, Sb, Bi, Se and Te, characterized in that the polyoxometalate is supported on a solid support selected from the group consisting of Al2O3, MgO, TiO2, ZrO2, SiO2, mesoporous silica, active carbon, diatomite, clays, zeolites, polyoxometalate salts and mixtures thereof, with the proviso that the polyoxometalate salt supports are different from the supported polyoxometalates defined by the above formula, a process for their preparation and their use for the catalytic oxidation of organic molecules.
    Type: Application
    Filed: May 31, 2006
    Publication date: December 6, 2007
    Inventors: Ryan M. Richards, Ulrich Kortz, Lihua Bi, Kake Zhu
  • Publication number: 20070282139
    Abstract: The invention relates to polyoxometalates represented by the formula (An)m+ [My(H2O)(p.y)X2W22O74(OH)2]m? or solvates or mixtures thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyoxoanion, M represents a transition metal selected from Pd, Pt and mixtures thereof, y is 1, 2, 3 or 4, p is the number of water molecules bound to one M and varies from 3 to 5, and X represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV, a process for their preparation and their use for the catalytic oxidation of organic molecules.
    Type: Application
    Filed: May 31, 2006
    Publication date: December 6, 2007
    Inventors: Ulrich Kortz, Lihua Bi