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Patent number: WO 2018202420A1Abstract: The invention relates to polyoxometalates represented by the formula (A n )m+[M’M 12 O y (RCOO) z H q ] m- or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.Type: ApplicationFiled: April 17, 2018Date of Patent:Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ma, Tian; Kortz Ulrich; Yang Peng; Lin Zhengguo; Ayass Wassim Walid
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Patent number: WO 2018162144A1Abstract: The invention relates to polyoxometalates represented by the formula (An)m+[M’M12X8OyRzHq]m- or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.Type: ApplicationFiled: January 25, 2018Date of Patent:Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ma, Tian; Kortz Ulrich; Yang Peng; Lin Zhengguo; Ayass Wassim Walid
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Patent number: US 20190030517A1Abstract: The invention relates to poly oxometalates represented by the formula (A n ) m+ {M′ s [M″M 15 X 10 O y R z H q ]} m− or solvates thereof, corresponding supported poly-oxometalates, and processes for their preparation, as well as corresponding metal-clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.Type: ApplicationFiled: January 19, 2017Date of Patent:Assignee: ExxonMobil Chemical Patents Inc.Inventors: Kortz Ulrich; Xiang Yixian; Lin Zhengguo; Yang Peng; Jaensch Helge; Ayass Wassim Walid
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Patent number: US 20190091663A1Abstract: The invention relates to polyoxometalates represented by the formula (An)m+{M’s[M”M12X8OyRzHq]}m- or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal-clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.Type: ApplicationFiled: October 14, 2016Date of Patent:Assignee: ExxonMobil Chemical Patents Inc.Inventors: Kortz Ulrich; Xiang Yixian; Lin Zhengguo; Yang Peng; Jaensch Helge; Ayass Wassim Walid
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Publication number: US 20170150725Abstract: The present invention relates to the use of heteropolyoxometalates for disinfecting purposes and in antimicrobial surfaces, paints or coatings and intermediates for their preparation.Type: ApplicationFiled: February 6, 2014Publication date: June 1, 2017Applicant: POM Patentverwaltungs GbRInventors: Klaus Schepers, Horst Mischo, Pierre-Alain Weiss, Ulrich Kortz, Bassem S. Bassil, Maria Barsukova-Stuckart, Rami Al-Oweini, Andreas Suchopar, Ali Haider, Alexander Birkel, Balamurugan Kandasamy
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Patent number: US 8080493Abstract: The invention relates to polyoxometalates represented by the formula (An)m+ [M13X8RqOy]m- or solvates thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyanion, M represents a transition metal selected from Pd, Pt, Au, Rh, Ir and mixtures thereof, X represents a heteroatom selected from As, Sb, Bi, P, Si, Ge, B, Al, Ga, S, Se, Te and mixtures thereof, and y is the number of oxygen atoms ranging from 32 to 40, a process for their preparation and their use for the catalytic oxidation of organic molecules.Type: GrantFiled: February 26, 2008Date of Patent: December 20, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Elena Vladimirovna Chubarova, Ulrich Kortz
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Patent number: US 7906686Abstract: In a process for producing hydroperoxides, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of a catalyst comprising a polyoxometalate to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I) and wherein the polyoxometalate comprises a polyoxotungstate substituted with at least one further transition metal.Type: GrantFiled: April 7, 2008Date of Patent: March 15, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Helge Jaensch, Jihad M. Dakka, Francisco M. Benitez, Ulrich Kortz, Ryan Matthew Richards
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Patent number: US 7858814Abstract: The invention relates to polyoxometalates represented by the formula (An)m+ [Ru2L2(XW11O39)2WO2]m- or solvates thereof, wherein A is a cation, n is the number of the cations, m is the charge of the polyanion, L is a ligand bound to ruthenium and is independently selected from group consisting of water, unsubstituted or substituted arenes, unsubstituted or substituted heteroarenes, unsaturated hydrocarbons, ethers, unsubstituted or substituted allyl, unsubstituted or substituted alkanes, nitriles, carboxylates, peroxides, peracids, phosphines, phosphanes, CO, OH?, peroxo, carbonate, NO3?, NO2?, NO?, NH3, amines, F?, Cl?, Br?, I?, SCN?, NCS?, NCO? and mixtures thereof and X is a heteroatom selected from Si, Ge, B and mixtures thereof, a process for their preparation and their use for the catalytic oxidation of organic molecules.Type: GrantFiled: June 20, 2008Date of Patent: December 28, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ulrich Kortz, Elena Vladimirovna Chubarova, Nadeen Hassan Nsouli
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Patent number: US 7820868Abstract: This invention relates to polyoxometalates represented by the formula (An)m+[My(H2O)pXzZ2W18O66]m- or solvates thereof, wherein A represents a cation acting as counterion of the polyanion, n is the number of the cations A, m is the charge of the polyoxoanion, M represents a transition metal selected from Cu, Zn, Pd, Pt and mixtures thereof, y is the number of transition metals M and is a number from greater than 4 to less than 6, p is a number of water molecules and is a number from 0 to 10, X is a halide selected from F, Cl, Br, I and mixtures thereof, z is a number of halides and is a number from 0 to 6 and Z represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV.Type: GrantFiled: January 19, 2007Date of Patent: October 26, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ulrich Kortz, Sib Sankar Mal
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Patent number: US 7645907Abstract: This invention relates to a Polyoxometalate (POM) represented by the formula: (An)m+[HqM16X8W48O184(OH)32]m- or solvates thereof, wherein: A represents a cation, n is the number of the cations A, m is the charge of the polyoxoanion, q is the number of protons and varies from 0 to 12, M represents a transition metal, and X represents a heteroatom selected from P, As and mixtures thereof. This invention also relates to a process to produce such POMs and to a process for the homogeneous or heterogeneous oxidation of organic substrates comprising contacting the organic substrate with such POMs.Type: GrantFiled: March 23, 2007Date of Patent: January 12, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ulrich Kortz, Sib Sankar Mal
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Patent number: US 7514577Abstract: The invention relates to polyoxometalates represented by the formula (An)m+ [My(H2O)(p.y)X2W22O74(OH)2]m- or solvates or mixtures thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyoxoanion, M represents a transition metal selected from Pd, Pt and mixtures thereof, y is 1, 2, 3 or 4, p is the number of water molecules bound to one M and varies from 3 to 5, and X represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV, a process for their preparation and their use for the catalytic oxidation of organic molecules.Type: GrantFiled: May 31, 2006Date of Patent: April 7, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ulrich Kortz, Lihua Bi
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Patent number: US 7417008Abstract: The invention relates to supported polyoxometalates represented by the formula (An)m+ [M4(H2O)10(XW9O33)2]m- or solvates thereof, wherein A represents a cation, n is the number of cations, m is the charge of the polyoxoanion, M is a transition metal, and X is an element selected from the group consisting of As, Sb, Bi, Se and Te, characterized in that the polyoxometalate is supported on a solid support selected from the group consisting of Al2O3, MgO, TiO2, ZrO2, SiO2, mesoporous silica, active carbon, diatomite, clays, zeolites, polyoxometalate salts and mixtures thereof, with the proviso that the polyoxometalate salt supports are different from the supported polyoxometalates defined by the above formula, a process for their preparation and their use for the catalytic oxidation of organic molecules.Type: GrantFiled: May 31, 2006Date of Patent: August 26, 2008Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ryan M. Richards, Ulrich Kortz, Lihua Bi, Kake Zhu
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Patent number: US 7358380Abstract: The invention relates to polyoxometalates represented by the formula (An)m+[R2(H2O)6X2W20O70]m- or solvates thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyoxoanion, and X represents a heteroatom selected from SbIII, BiIII, AsIII, SeIV and TeIV, a process for their preparation and their use for the catalytic oxidation of organic molecules.Type: GrantFiled: May 31, 2006Date of Patent: April 15, 2008Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ulrich Kortz, Lihua Bi